重庆理工大学学报(自然科学) ›› 2023, Vol. 37 ›› Issue (4): 133-140.

• 机械·材料 • 上一篇    下一篇

补锂粘结剂羧甲基纤维素锂(CMCLi)的合成与应用研究

邱 磊,李 富,杨 稳   

  1. 1.重庆理工大学 化学化工学院,重庆 400054; 2.重庆亿隆涂料股份有限公司,重庆 402260; 3.绿能纤材(重庆)科技有限公司,重庆 40005
  • 出版日期:2023-05-06 发布日期:2023-05-06
  • 作者简介:邱磊,男,博士,主要从事锂电池粘结剂的改性和复配领域的研究,Email:qiulei1010@cqut.edu.cn

Study on synthesis and application of lithium carboxymethyl cellulose (CMC-Li) as lithium replenishing binder

  • Online:2023-05-06 Published:2023-05-06

摘要: 以纤维素粉和乙醇锂为原材料,通过 IR分析显示成功合成得到羧甲基纤维素锂 (CMCLi)。分别以 CMCLi和羧甲基纤维素钠(CMCNa)作为锂离子电池负极粘结剂进行研 究,发现 CMCLi表现出比较优秀的悬浮和分散性能,不与电解液发生反应,稳定性好。同时,在 相同条件下,CMCLi可以提高电极的压实密度、吸液速率和吸液量,减少极化现象,降低内阻 10%左右,减少物理反弹约 14.5%,使得充放电比容量提高约 1%,剥离强度提高约 9.8%,首效 提高约 2%,循环寿命延长约 12%,有着非常优秀的补锂效果。

关键词: 乙醇锂, 羧甲基纤维素锂, 粘结剂, 补锂效果, 锂离子电池

Abstract: By using cellulose powder and lithium ethoxide as the raw materials, this paper successfully synthesizes lithium carboxymethyl cellulose (CMC-Li) through IR analysis. With CMC-Li and sodium carboxymethyl cellulose (CMC-Na) being respectively used as the negative electrode binder for lithium-ion batteries, it is found that CMC-Li displays excellent suspension and dispersion performance and does not react with the electrolyte, which shows a good stability. At the same time, under the same conditions, CMC-Li can improve the compaction density of the electrode, increase the liquid absorption rate and amount, reduce the polarization, decrease the internal resistance by about 10% and decrease the physical rebound by about 14.5%. The specific capacity of charge and discharge increases by about 1%, the peeling strength increases by about 9.8%, the first effect increases by about 2%, and the cycle life is extended by about 12%. It has a very excellent lithium supplementation effect.

中图分类号: 

  • TQ340.6